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Author(s):   Harris, S.J.; Kerr, J.A.
Title:   Relative rate measurements of some reactions of hydroxyl radicals with alkanes studied under atmospheric conditions
Journal:   Int. J. Chem. Kinet.
Volume:   20
Year:   1988
Reference type:   Journal article
Squib:   1988HAR/KER939

Reaction:   (CH3)2CHCH(CH3)2 + ·OH → Other Products + H2O
Reaction order:   2
Reference reaction:   n-C5H12 + ·OH → Other Products + H2O
Reference reaction order:   2
Temperature:   247 - 327 K
Pressure:  1.33E-3 bar
Rate expression:   4.11x10-1 e3093 [±557 J/mole]/RT
Uncertainty:   1.26999998
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
247 1.85E0
250 1.82E0
275 1.59E0
300 1.42E0
325 1.29E0
327 1.28E0