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Author(s):   He, Y.Z.; Cui, J.P.; Mallard, W.G.; Tsang, W.
Title:   Homogeneous gas-phase formation and destruction of anthranil from o-nitrotoluene decomposition
Journal:   J. Am. Chem. Soc.
Volume:   110
Year:   1988
Reference type:   Journal article
Squib:   1988HE/CUI3754

Reaction:   Benzene, 1-methyl-4-nitro- → Phenyl, 4-methyl- + NO2
Reaction order:   1
Temperature:   1000 - 1170 K
Pressure:  2.03 - 4.05 bar
Rate expression:   7.69x1014 [s-1] e-268557 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 7.21E0
1025 1.59E1
1050 3.36E1
1075 6.87E1
1100 1.36E2
1125 2.61E2
1150 4.87E2
1170 7.88E2