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Accessibility information
Author(s):   Heicklen, J.
Title:   The decomposition of alkyl nitrites and the reactions of alkoxyl radicals
Journal:   Adv. Photochem.
Volume:   14
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988HEI177

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1988HEI177   CH3O2· + CH3 → Products  298 - 450   2.62E-12           2.62E-12  2
  1988HEI177   CH3CH2O +   298 - 450   2.00E14       1.05E05   8.67E-05  1
  1988HEI177   CH3 + CH3 → Products  298 - 413   3.32E-11           3.32E-11  2
  1988HEI177   CH3 + ·CH3 → Products  298 - 450   2.62E-11           2.62E-11  2
  1988HEI177   CH3 + O2CH2O + HO2  298 - 628   8.52E-14       1.07E04   1.12E-15  2
  1988HEI177   CH3 + NOCH3ONO  298   1.66E-11           1.66E-11  2
  1988HEI177   CH3 + CH3C(O)O → Products  298 - 450   7.26E-11           7.26E-11  2
  1988HEI177   CH3 + → Products  298   2.14E-11           2.14E-11  2
  1988HEI177   CH3CH2CH2O + ·CH3  298 - 450   1.00E15       9.06E04   0.13  1
  1988HEI177   CH3CH2CH3CHO +   298 - 450   2.00E14       9.73E04   1.78E-03  1
  1988HEI177   CH3CH2 + O2CH3CHO + HO2  225 - 425   1.62E-13       6652   1.11E-14  2
  1988HEI177   CH3CH2 + NOC2H5ONO  298   2.62E-11           2.62E-11  2
  1988HEI177   (CH3)3CO· → Acetone + ·CH3  298 - 450   1.00E15       6.90E04   801  1
  1988HEI177   (CH3)3CO· + (CH3)3CO· → Products  298   2.14E-12           2.14E-12  2
  1988HEI177   i-C3H7OAcetone +   298 - 450   2.00E14       8.98E04   0.04  1
  1988HEI177   i-C3H7OCH3CHO + ·CH3  298 - 450   1.00E15       7.33E04   145  1
  1988HEI177   i-C3H7O + O2Acetone + HO2  298 - 383   8.14E-14       6652   5.55E-15  2
  1988HEI177   i-C3H7O + NOi-C3H7ONO  298   3.32E-11           3.32E-11  2
  1988HEI177   O2 + n-C3H7OC2H5CHO + HO2  250 - 361   3.24E-13       8281   1.14E-14  2
  1988HEI177   O2 + CH3CH2CH2CH2CH3CH2CH2CHO + HO2  296 - 361   3.24E-13       8281   1.14E-14  2
  1988HEI177   O2 + (CH3)2CHCH2O· → (CH3)2CHCHO + HO2  265 - 361   3.24E-13       8281   1.14E-14  2
  1988HEI177   NO + C2H5C(CH3)2O(·) → C2H5C(CH3)2ONO  298   3.32E-11           3.32E-11  2
  1988HEI177   NO + n-C3H7On-C3H7ONO  298   3.32E-11           3.32E-11  2
  1988HEI177   NO + CH3CH2CH2CH2n-C4H9ONO  298   3.32E-11           3.32E-11  2
  1988HEI177   NO + (CH3)2CHCH2O· → (CH3)2CHCH2ONO  298   3.32E-11           3.32E-11  2
  1988HEI177   NO + n-C5H11O· → n-C5H11ONO  298   3.32E-11           3.32E-11  2
  1988HEI177   NO + CH3CH2CH(CH3)O· → CH3CH2CH(CH3)ONO  298   3.32E-11           3.32E-11  2
  1988HEI177   C2H5C(CH3)2O(·) → Acetone + ·C2H5  298 - 450   1.00E15       6.40E04   6002  1
  1988HEI177   C2H5C(CH3)2O(·) → C2H5COCH3 + ·CH3  298 - 450   1.00E15       7.82E04   19.33  1
  1988HEI177   ·F + CF3OCF3OF  298   5.76E-11           5.76E-11  2
  1988HEI177   CH3CH2CH(CH3)O· → CH3CHO + ·C2H5  298 - 450   1.00E15       6.44E04   5075  1
  1988HEI177   CH3CH2CH(CH3)O· → C2H5CHO + ·CH3  298 - 450   1.00E15       7.99E04   9.88  1
  1988HEI177   CH3(CH2)2CH(CH3)O → CH3CHO + 1-C3H7  298 - 450   1.00E15       6.44E04   5075  1

Search returned 33 records.