Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: The decomposition of alkyl nitrites and the reactions of alkoxyl radicals
Journal: Adv. Photochem.
Volume: 14
Page(s):
Year: 1988
Reference type: Journal article
Squib: 1988HEI177
Reaction:
C2H5C(CH3)2O(·) → (CH3)2CO + ·C2H5
Reaction order:
1
Temperature:
298 - 450
K
Rate expression:
1.0x1015 [s-1] e-64021 [J/mole]/RT
Category: Review
Data type:
Extensive literature review
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 298 | 6.00E3 |
| 300 | 7.13E3 |
| 325 | 5.14E4 |
| 350 | 2.79E5 |
| 375 | 1.21E6 |
| 400 | 4.36E6 |
| 425 | 1.35E7 |
| 450 | 3.70E7 |