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Accessibility information
Author(s):   Herron, J.T.
Title:   Evaluated chemical kinetic data for the reactions of atomic oxygen O(3P) with saturated organic compounds in the gas phase
Journal:   J. Phys. Chem. Ref. Data
Volume:   17
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988HER967

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1988HER967   CH2O + HCO + ·OH  250 - 800   2.99E-11       1.28E04   1.70E-13  2
  1988HER967   CH2O + HCO + ·OH  800 - 2000   3.45E-12   1.94   4340      2
  1988HER967   CCl4 + ·CCl3 + ClO  300 - 1000   4.98E-13       1.83E04      2
  1988HER967   (C2H5)2O + → Other Products + ·OH  300 - 500   9.96E-11       1.66E04      2
  1988HER967   C2H5OH + → Other Products + ·OH  300 - 1000   1.22E-12   2.46   7732      2
  1988HER967   CH3OH + → Other Products + ·OH  1000 - 2000   6.11E-13   2.50   1.29E04      2
  1988HER967   CH3OH + → Other Products + ·OH  300 - 1000   3.32E-11       2.10E04      2
  1988HER967   iso-C3H7OH + → Other Products + ·OH  298   6.64E-14           6.64E-14  2
  1988HER967   Acetone + CH3C(O)CH2(·) + ·OH  300 - 700   1.66E-11       2.49E04      2
  1988HER967   CHCl3 + ·CCl3 + ·OH  300 - 1000   4.98E-12       2.08E04      2
  1988HER967   n-C3H7OH + → Other Products + ·OH  298   4.98E-14           4.98E-14  2
  1988HER967   n-C4H9OH + → Other Products + ·OH  300 - 600   4.98E-11       1.50E04      2
  1988HER967   CH4 + ·CH3 + ·OH  400 - 2500   8.30E-12   1.56   3.55E04      2
  1988HER967   CH3Br + ·OH + ·CH2Br  400 - 1500   3.32E-11       3.24E04      2
  1988HER967   C2H6 + ·C2H5 + ·OH  1100 - 2000   3.89E-12   2.40   2.44E04      2
  1988HER967   C2H6 + ·C2H5 + ·OH  400 - 1100   1.83E-10       3.28E04      2
  1988HER967   CH3Cl + ·OH + ·CH2Cl  400 - 1500   3.32E-11       3.24E04      2
  1988HER967   CH3NH2 + → Products  300 - 600   8.97E-12       6901      2
  1988HER967   C2H5Br + → Other Products + ·OH  340 - 650   5.15E-11       2.71E04      2
  1988HER967   C3H8 + → Other Products + ·OH  1100 - 2000   3.64E-13   3.50   1.06E04      2
  1988HER967   C3H8 + → Other Products + ·OH  400 - 1100   1.66E-10       2.64E04      2
  1988HER967   C2H5Cl + → Other Products + ·OH  340 - 650   7.97E-11       2.77E04      2
  1988HER967   C2H5NH2 + → Products  300 - 600   1.13E-11       5321      2
  1988HER967   CH3CHO + → Other Products + ·OH  300 - 500   1.19E-11       8231      2
  1988HER967   CH2Cl2 + ·OH + CHCl2  300 - 1000   9.96E-12       2.41E04      2
  1988HER967   Cyclopropane + Cyclopropyl + ·OH  298   8.30E-16           8.30E-16  2
  1988HER967   Oxirane + ·OH + Oxiranyl  298   6.64E-17           6.64E-17  2
  1988HER967   (CH3)3NBH3 + → Products  300 - 2000   4.98E-11              2
  1988HER967   iso-C3H7Br + ·OH + (CH3)2CBr  340 - 650   3.82E-11       2.24E04      2
  1988HER967   iso-C4H10 + → Other Products + ·OH  1000 - 2000   6.44E-14   3.90   665      2
  1988HER967   iso-C4H10 + → Other Products + ·OH  400 - 1000   9.47E-11       2.20E04      2
  1988HER967   iso-C3H7Cl + ·OH + (CH3)2CCl  300 - 700   3.99E-11       2.13E04      2
  1988HER967   CH3CHCl2 + → Other Products + ·OH  300 - 700   4.98E-12       2.03E04      2
  1988HER967   CHFCl2 + ·CCl2F + ·OH  300 - 1000   1.66E-11       3.08E04      2
  1988HER967   COCl2 + ClCO + ClO  292   9.96E-15              2
  1988HER967   CHF2Cl + ·CClF2 + ·OH  300 - 1000   1.16E-11       3.49E04      2
  1988HER967   CHF3 + ·CF3 + ·OH  300 - 1000   8.30E-12       4.49E04      2
  1988HER967   (CH3)3N + → Products  300 - 600   1.08E-11       -1746      2
  1988HER967   CF3Br + ·CF3 + BrO  500 - 1500   1.49E-11       5.65E04      2
  1988HER967   tert-C4H9OH + → Other Products + ·OH  300 - 600   8.30E-12       1.83E04      2
  1988HER967   CH3CF2Cl + → Other Products + ·OH  298   6.64E-17           6.64E-17  2
  1988HER967   CF3CH2Cl + ·OH + CF3CHCl  300 - 700   3.32E-12       2.16E04      2
  1988HER967   iso-C4H9Br + → Other Products + ·OH  340 - 600   5.65E-11       2.09E04      2
  1988HER967   iso-C5H12 + → Other Products + ·OH  307   1.33E-13              2
  1988HER967   iso-C4H9OH + → Other Products + ·OH  300 - 600   6.14E-12       9146      2
  1988HER967   (CH3)2CHCHO + → Other Products + ·OH  300 - 500   1.31E-11       6070      2
  1988HER967   sec-C4H9Cl + → Other Products + ·OH  340 - 650   5.98E-11       2.10E04      2
  1988HER967   sec-C4H9OH + → Other Products + ·OH  300 - 600   7.47E-12       9977      2
  1988HER967   C2H5COCH3 + → Other Products + ·OH  300 - 600   8.30E-13       1.08E04      2
  1988HER967   CH3C(O)OCH3 + → Other Products + ·OH  300 - 500   1.66E-11       2.41E04      2
  1988HER967   (CH3)2CHCH(CH3)2 + → Other Products + ·OH  300 - 2000   3.09E-13   3.60   1164      2
  1988HER967   (C2H5)2CO + → Other Products + ·OH  300 - 600   4.98E-13       8314      2
  1988HER967   1-C4H10 + → Other Products + ·OH  300 - 2000   3.49E-13   3.90   6485      2
  1988HER967   CH2ClCH2Cl + ·OH + CH2ClCHCl·  300 - 700   8.30E-12       2.08E04      2
  1988HER967   HC(O)OCH3 + → HC(O)OCH2(·) + ·OH  300 - 500   1.49E-11       2.24E04      2
  1988HER967   Pentane, 2,4-dimethyl- + → Other Products + ·OH  307   1.66E-13              2
  1988HER967   Cyclohexanone + → Other Products + ·OH  300 - 600   4.98E-11       1.91E04      2
  1988HER967   CH3COOCH2CH2CH3 + → Other Products + ·OH  300 - 500   2.66E-11       2.00E04      2
  1988HER967   n-C4H9Br + → Other Products + ·OH  340 - 650   7.31E-11       2.23E04      2
  1988HER967   n-C5H12 + → Other Products + ·OH  300 - 2000   1.68E-12   3.00   8398      2
  1988HER967   HC(O)OC2H5 + → Other Products + ·OH  300 - 500   1.66E-11       2.16E04      2
  1988HER967   Tetrahydrofuran + → Other Products + ·OH  300 - 600   1.33E-10       1.58E04      2
  1988HER967   1-C6H14 + → Other Products + ·OH  300 - 2000   2.49E-12   2.90   8314      2
  1988HER967   Cyclohexane + Cyclohexyl + ·OH  300 - 2000   1.17E-11   2.60   1.07E04      2
  1988HER967   n-C8H18 + → Other Products + ·OH  300 - 2000   2.67E-12   2.80   6984      2
  1988HER967   (CH3)2O + ·OH + CH3OCH2  300 - 500   8.30E-11       1.91E04      2
  1988HER967   Cyclopentanone + → Other Products + ·OH  300 - 600   3.99E-11       1.91E04      2
  1988HER967   C2H5CHO + → Other Products + ·OH  300 - 500   1.30E-11       7234      2
  1988HER967   CH3CH2CH2CHO + → Other Products + ·OH  300 - 500   1.66E-11       7150      2
  1988HER967   (CH3)2NH + → Products  300 - 600   1.51E-11       2328      2
  1988HER967   CH3C(O)OC2H5 + → Other Products + ·OH  300 - 500   2.32E-11       2.08E04      2
  1988HER967   Tetrahydro-2H-pyran + → Other Products + ·OH  300 - 600   9.96E-11       1.50E04      2
  1988HER967   1-C7H16 + → Other Products + ·OH  300 - 2000   2.31E-12   2.90   7317      2
  1988HER967   Spiropentane + ·OH + Spiropentyl  298 - 650   6.64E-11       2.40E04   4.08E-15  2
  1988HER967   Cyclobutane + ·OH + Cyclobutyl  298   1.16E-14           1.16E-14  2
  1988HER967   Cyclopentane + ·OH + Cyclopentyl  300 - 2000   1.30E-11   2.60   1.16E04      2
  1988HER967   Cycloheptane + ·OH + Cycloheptyl  300 - 2000   9.45E-12   2.60   9063      2
  1988HER967   neo-C5H12 + ·OH + Neopentyl  1000 - 2000   3.57E-12   2.50   2.26E04      2
  1988HER967   neo-C5H12 + ·OH + Neopentyl  400 - 1000   1.53E-10       2.99E04      2
  1988HER967   tert-C4H9Cl + ·OH + (CH3)2CClCH2  340 - 650   4.32E-11       2.50E04      2
  1988HER967   iso-C4H9Cl + → Other Products + ·OH  340 - 650   5.98E-11       2.10E04      2
  1988HER967   (CH3)2CHCH2C(CH3)3 + → Other Products + ·OH  307   9.13E-14              2
  1988HER967   2,3,4-Trimethylpentane + → Other Products + ·OH  307   4.98E-14              2
  1988HER967   Pentane, 2,2-dimethyl- + → Other Products + ·OH  307   1.08E-13              2
  1988HER967   CH2FCl + ·OH + ·CClFH  300 - 1000   8.30E-12       2.58E04      2
  1988HER967   (CH3)2Hg + → Products  298   2.49E-11           2.49E-11  2
  1988HER967   (CH3)3CC(CH3)3 + ·OH + (CH3)3CC(CH3)2CH2  300 - 2000   8.15E-12   2.50   2.14E04      2
  1988HER967   t-C4H9CH2Cl + → Other Products + ·OH  340 - 650   5.31E-11       2.22E04      2
  1988HER967   (CH3)3SiH + ·OH + (CH3)3Si·  298   2.66E-12           2.66E-12  2
  1988HER967   (CH3)6Si2 + → Products  298   1.30E-13           1.30E-13  2
  1988HER967   tert-C4H9 + → Products  300 - 2000   8.30E-10              2
  1988HER967   ·CClF + → Products  298   1.66E-11           1.66E-11  2
  1988HER967   (C2H5)3NBH3 + → Products  300 - 2000   4.98E-11              2
  1988HER967   FCO + → Products  300 - 2000   9.96E-11              2
  1988HER967   iso-C3H7 + → Products  300 - 2000   4.98E-10              2
  1988HER967   CH3O2· + CH3 + O2  300 - 2000   8.30E-11              2
  1988HER967   1-C3H7 + → Products  300 - 2000   3.32E-10              2
  1988HER967   CH3 + → Products  300 - 2000   3.32E-11              2
  1988HER967   ·CF2 + → Products  298   1.66E-11           1.66E-11  2
  1988HER967   ·CH3 + CH2O +   300 - 2000   1.39E-10              2
  1988HER967   ·CF3 + COF2 + ·F  298   3.32E-11           3.32E-11  2
  1988HER967   CF3I + ·CF3 + IO  300 - 1500   1.16E-11              2
  1988HER967   CH3CH(·)OH + → Products  300 - 2000   1.66E-10              2
  1988HER967   (·)CH2OH + → Products  300 - 2000   8.30E-11              2
  1988HER967   HCO + → Products  300 - 2000   9.96E-11              2
  1988HER967   Cyclohexyl + → Products  300 - 2000   3.32E-10              2
  1988HER967   CH3CO + → Products  300 - 2000   9.96E-11              2
  1988HER967   ·CCl3 + COCl2 + ·Cl  298   4.15E-11           4.15E-11  2
  1988HER967   ·CH + → Products  300 - 2000   9.96E-11              2
  1988HER967   Neopentyl + → Products  300 - 2000   3.32E-10              2
  1988HER967   ·CCl + CO + ·Cl  300 - 2000   9.96E-11              2
  1988HER967   iso-C4H9 + → Products  300 - 2000   3.32E-10              2
  1988HER967   (CH3)2C(OH) + → Products  300 - 2000   8.30E-11              2
  1988HER967   GeH4 + ·OH + GeH3  298   3.32E-12           3.32E-12  2
  1988HER967   SiH4 + ·OH + SiH3  300 - 1000   6.64E-12       6652      2
  1988HER967   BH3CO + → Products  298   6.64E-13           6.64E-13  2
  1988HER967   ·CHF + → Products  300 - 2000   1.49E-10              2
  1988HER967   ·C2H5 + → Products  300 - 2000   2.16E-10              2
  1988HER967   + Diborane(6) → Products  300 - 1000   1.66E-11       2.08E04      2
  1988HER967   + (CH3)2CCl → Products  300 - 2000   1.66E-10              2
  1988HER967   + n-C7H15Cl → Other Products + ·OH  298   1.33E-13           1.33E-13  2
  1988HER967   + ·CH2 → Products  300 - 2000   1.33E-10              2

Search returned 122 records.