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Accessibility information
Author(s):   Kern, R.D.; Singh, H.J.; Wu, C.H.
Title:   Thermal decomposition of 1,2 butadiene
Journal:   Int. J. Chem. Kinet.
Volume:   20
Year:   1988
Reference type:   Journal article
Squib:   1988KER/SIN731

Reaction:   1,3-ButadieneC2H3 + C2H3
Reaction order:   1
Temperature:   1300 - 2000 K
Pressure:  0.20 - 0.56 bar
Rate expression:   3.07x1012 [s-1] e-278535 [J/mole]/RT
Bath gas:   Ne
Category:  Experiment
Data type:   Derived from detailed balance/reverse rate

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1300 1.98E1
1350 5.13E1
1400 1.24E2
1450 2.84E2
1500 6.14E2
1550 1.26E3
1600 2.48E3
1650 4.67E3
1700 8.49E3
1750 1.49E4
1800 2.54E4
1850 4.20E4
1900 6.76E4
1950 1.06E5
2000 1.63E5