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Author(s):   Lam, W.W.; Yokota, T.; Safarik, I.; Strausz, O.P.
Title:   Photolysis of, and the reactions of H-atoms with, isopropanethiol
Journal:   Can. J. Chem.
Volume:   66
Year:   1988
Reference type:   Journal article
Squib:   1988LAM/YOK2025

Reaction:   iso-C3H7SH + H2 + (CH3)2CHS
Reaction order:   2
Reference reaction:   iso-C3H7SH + iso-C3H7 + H2S
Reference reaction order:   2
Temperature:   298 - 418 K
Pressure:  1.33E-4 - 0.53 bar
Rate expression:   1.43±5.7x10-2 e6402 [±320 J/mole]/RT
Bath gas:   n-C4H10
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 1.89E1
300 1.86E1
325 1.53E1
350 1.29E1
375 1.11E1
400 9.80E0
418 9.02E0