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Author(s):   Lam, W.W.; Yokota, T.; Safarik, I.; Strausz, O.P.
Title:   Photolysis of, and the reactions of H-atoms with, isopropanethiol
Journal:   Can. J. Chem.
Volume:   66
Year:   1988
Reference type:   Journal article
Squib:   1988LAM/YOK2025

Reaction:   iso-C3H7SH + iso-C3H7 + H2S
Reaction order:   2
Reference reaction:   iso-C3H7SH + H2 + (CH3)2CHS
Temperature:   298 - 418 K
Pressure:  1.33E-4 - 0.53 bar
Rate expression:   4.62x10-12 [±9.3x10-13 cm3/molecule s] e-10892 [±435 J/mole]/RT
Bath gas:   iso-C4H10
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 5.69E-14
300 5.86E-14
325 8.20E-14
350 1.09E-13
375 1.40E-13
400 1.75E-13
418 2.01E-13