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Author(s):   Larson, c.W.; Stewart, P.H.; Golden, D.M.
Title:   Pressure and temperature dependence of reactions proceeding via a bound complex. An approach for combustion and atmospheric chemistry modelers. Application to HO + CO →’ [HOCO] →’ H + CO2
Journal:   Int. J. Chem. Kinet.
Volume:   20
Year:   1988
Reference type:   Journal article
Squib:   1988LAR/STE27

Reaction:   CO + ·OHCO2 +
Reaction order:   2
Temperature:   200 - 2200 K
Pressure:  1.33E-4 - 1.33 bar
Rate expression:   4.35x10-14 [cm3/molecule s] (T/298 K)1.35 e3035 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
200 1.58E-13
300 1.48E-13
400 1.61E-13
500 1.82E-13
600 2.06E-13
700 2.32E-13
800 2.60E-13
900 2.90E-13
1000 3.21E-13
1100 3.53E-13
1200 3.87E-13
1300 4.21E-13
1400 4.56E-13
1500 4.92E-13
1600 5.28E-13
1700 5.66E-13
1800 6.04E-13
1900 6.43E-13
2000 6.82E-13
2100 7.23E-13
2200 7.63E-13