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Accessibility information
Author(s):   Larson, c.W.; Stewart, P.H.; Golden, D.M.
Title:   Pressure and temperature dependence of reactions proceeding via a bound complex. An approach for combustion and atmospheric chemistry modelers. Application to HO + CO →’ [HOCO] →’ H + CO2
Journal:   Int. J. Chem. Kinet.
Volume:   20
Year:   1988
Reference type:   Journal article
Squib:   1988LAR/STE27

Reaction:   HCOO → CO2 +
Reaction order:   1
Temperature:   200 - 2200 K
Pressure:  1.33E-4 - 1.33 bar
Rate expression:   1.0x1013 [s-1] (T/298 K)0.31 e-138020 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
200 7.95E-24
300 9.33E-12
400 1.04E-5
500 4.47E-2
600 1.20E1
700 6.53E2
800 1.32E4
900 1.37E5
1000 8.96E5
1100 4.17E6
1200 1.51E7
1300 4.47E7
1400 1.14E8
1500 2.57E8
1600 5.23E8
1700 9.80E8
1800 1.72E9
1900 2.84E9
2000 4.46E9
2100 6.72E9
2200 9.76E9