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Author(s):   Liu, A.; Mulac, W.A.; Jonah, C.D.
Title:   Rate constants for the gas-phase reactions of OH radicals with 1,3-butadiene and allene at 1 atm in Ar and over the temperature range 305-1173 K
Journal:   J. Phys. Chem.
Volume:   92
Year:   1988
Reference type:   Journal article
Squib:   1988LIU/MUL131

Reaction:   1,3-Butadiene + ·OH → Products
Reaction order:   2
Temperature:   313 - 623 K
Pressure:  1.01 bar
Rate expression:   1.4x10-11 [±9.8x10-13 cm3/molecule s] e3658 [±329 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Chemical activation
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
313 5.71E-11
325 5.42E-11
350 4.92E-11
375 4.53E-11
400 4.21E-11
425 3.94E-11
450 3.72E-11
475 3.53E-11
500 3.37E-11
525 3.24E-11
550 3.12E-11
575 3.01E-11
600 2.91E-11
623 2.84E-11