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Accessibility information
Author(s):   Liu, A.; Mulac, W.A.; Jonah, C.D.
Title:   Kinetic isotope effects in the gas-phase reaction of hydroxyl radicals with ethylene in the temperature range 343-1173 K and at 1-atm pressure
Journal:   J. Phys. Chem.
Volume:   92
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988LIU/MUL3828

Reaction:   C2H4 + ·OH → Products
Reaction order:   2
Reference reaction:   C2H4 + OD → Products
Reference reaction order:   2
Temperature:   300 - 2100 K
Pressure:  1.01 bar
Rate expression:   1.11 e200 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Chemical activation
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
300 1.20E0
400 1.18E0
500 1.16E0
600 1.16E0
700 1.15E0
800 1.14E0
900 1.14E0
1000 1.14E0
1100 1.13E0
1200 1.13E0
1300 1.13E0
1400 1.13E0
1500 1.13E0
1600 1.13E0
1700 1.13E0
1800 1.12E0
1900 1.12E0
2000 1.12E0
2100 1.12E0