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Accessibility information
Author(s):   Liu, A.; Mulac, W.A.; Jonah, C.D.
Title:   Kinetic isotope effects in the gas-phase reaction of hydroxyl radicals with ethylene in the temperature range 343-1173 K and at 1-atm pressure
Journal:   J. Phys. Chem.
Volume:   92
Year:   1988
Reference type:   Journal article
Squib:   1988LIU/MUL3828

Reaction:   C2D4 + ODD2O + CD2CD
Reaction order:   2
Temperature:   723 - 1170 K
Pressure:  1.01 bar
Rate expression:   2.57x10-13 [±5.15x10-15 cm3/molecule s] (T/298 K)2.13 e-10892 [J/mole]/RT
Bath gas:   Ar
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
723 2.78E-13
725 2.81E-13
750 3.20E-13
775 3.64E-13
800 4.10E-13
825 4.60E-13
850 5.14E-13
875 5.71E-13
900 6.32E-13
925 6.97E-13
950 7.66E-13
975 8.39E-13
1000 9.15E-13
1025 9.96E-13
1050 1.08E-12
1075 1.17E-12
1100 1.26E-12
1125 1.36E-12
1150 1.46E-12
1170 1.55E-12