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Accessibility information
Author(s):   Liu, A.; Mulac, W.A.; Jonah, C.D.
Title:   Kinetic isotope effects in the gas-phase reaction of hydroxyl radicals with ethylene in the temperature range 343-1173 K and at 1-atm pressure
Journal:   J. Phys. Chem.
Volume:   92
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988LIU/MUL3828

Reaction:   C2H4 + ·OH → Products
Reaction order:   2
Reference reaction:   C2D4 + ·OH → Products
Reference reaction order:   2
Temperature:   300 - 2100 K
Pressure:  1.01 bar
Rate expression:   9.91x10-1 e3401 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Chemical activation
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
300 3.87E0
400 2.76E0
500 2.25E0
600 1.96E0
700 1.78E0
800 1.65E0
900 1.56E0
1000 1.49E0
1100 1.44E0
1200 1.39E0
1300 1.36E0
1400 1.33E0
1500 1.30E0
1600 1.28E0
1700 1.26E0
1800 1.24E0
1900 1.23E0
2000 1.22E0
2100 1.20E0