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Accessibility information
Author(s):   Mitin, P.V.; Barabanov, V.G.; Volkov, G.V.
Title:   Kinetics of the thermal decomposition of 1,1-difluoro-1-chloroethane and 1,1,1-trifluoroethane
Journal:   Kinet. Catal.
Volume:   29
Page(s):   1279 - 1286
Original page:   1468
Year:   1988
Reference type:   Journal article
Squib:   1988MIT/BAR1279-1286

Reaction:   CH3CF3CH2=CF2 + HF
Reaction order:   1
Temperature:   1040 - 1100 K
Rate expression:   1.26x1013 [s-1] e-276872 [±2769 J/mole]/RT
Uncertainty:   1.25999999
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1040 1.57E-1
1050 2.12E-1
1075 4.44E-1
1100 8.98E-1