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Accessibility information
Author(s):   Mulder, P.; Louw, R.
Title:   Kinetic H/D isotope effects for gas phase hydroxylation of benzene and chlorobenzene between 520-1080 K. hydroxyl radical versus O(3P) atom attack
Journal:   Int. J. Chem. Kinet.
Volume:   20
Year:   1988
Reference type:   Journal article
Squib:   1988MUL/LOU577

Reaction:   Chlorobenzene + ·OH → Products
Reaction order:   2
Reference reaction:   ·OH + Benzene-d2, 4-chloro- → Products
Reference reaction order:   2
Temperature:   520 - 1080 K
Pressure:  1.01 bar
Rate expression:   7.24x10-1 e5180 [±8314472 J/mole]/RT
Uncertainty:   1.10000002
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
520 2.40E0
550 2.25E0
600 2.04E0
650 1.89E0
700 1.76E0
750 1.66E0
800 1.58E0
850 1.51E0
900 1.45E0
950 1.39E0
1000 1.35E0
1050 1.31E0
1080 1.29E0