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Accessibility information
Author(s):   Muller-Markgraf, W.; Troe, J.
Title:   Thermal decomposition of ethylbenzene, styrene, and bromophenylethane: UV absorption study in shock waves
Journal:   J. Phys. Chem.
Volume:   92
Year:   1988
Reference type:   Journal article
Squib:   1988MUL/TRO4914

Reaction:   Benzene, (1-bromoethyl)-Styrene + HBr
Reaction order:   1
Temperature:   900 - 1150 K
Pressure:  0.25 bar
Rate expression:   3.16x1012 [s-1] e-159638 [±9562 J/mole]/RT
Uncertainty:   1.58000004
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
900 1.72E3
925 3.06E3
950 5.28E3
975 8.86E3
1000 1.45E4
1025 2.32E4
1050 3.62E4
1075 5.53E4
1100 8.30E4
1125 1.22E5
1150 1.77E5