Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Perrin, D.; Richard, C.; Martin, R.
Title:   H2S-promoted thermal isomerization of Cis-2-pentene to 1-pentene and trans-2-pentene around 800 K
Journal:   Int. J. Chem. Kinet.
Volume:   20
Year:   1988
Reference type:   Journal article
Squib:   1988PER/RIC621

Reaction:   CH2CH=CHCH2CH31,3-Butadiene + ·CH3
Reaction order:   1
Reference reaction:   H2S + CH2CH=CHCH2CH31-C5H10 + SH
Reference reaction order:   2
Temperature:   743 - 772 K
Pressure:  1.33E-2 - 0.13 bar
Rate expression:   9.33x1026 [molecule/cm3] e-130537 [±3916 J/mole]/RT
Uncertainty:   1.70000005
Bath gas:   2-(Z)-C5H10
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [molecule/cm3]
743 6.21E17
750 7.57E17
772 1.37E18