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Author(s):   Rozenshtein, V.B.; Bedzhanyan, Yu.R.
Title:   Temperature dependences of the rates of the radical-radical reactions OH+NF2 and HO2+NF2
Journal:   Kinet. Catal.
Volume:   29
Year:   1988
Reference type:   Journal article
Squib:   1988ROZ/BED268

Reaction:   ·OH + NF2HF + FNO
Reaction order:   2
Temperature:   300 - 820 K
Pressure:  2.00E-3 - 1.13E-2 bar
Rate expression:   6.79x10-12 [±4.15x10-13 cm3/molecule s] e1912 [±249 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Electron spin resonance (ESR or EPR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 1.46E-11
350 1.31E-11
400 1.21E-11
450 1.13E-11
500 1.08E-11
550 1.03E-11
600 9.96E-12
650 9.67E-12
700 9.43E-12
750 9.23E-12
800 9.05E-12
820 8.99E-12