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Author(s):   Tschuikow-Roux, E.; Faraji, F.; Paddison, S.; Niedzielski, J.; Miyokawa, K.
Title:   Kinetics of photochlorination of halogen (F, Cl, Br) substituted methanes
Journal:   J. Phys. Chem.
Volume:   92
Page(s):   1488 - 1495
Year:   1988
Reference type:   Journal article
Squib:   1988TSC/FAR1488-1495

Reaction:   CH3Br + ClHCl + ·CH2Br
Reaction order:   2
Reference reaction:   CH4 + Cl·CH3 + HCl
Reference reaction order:   2
Temperature:   273 - 298 K
Pressure:  2.80E-2 bar
Rate expression:   1.91±9.6x10-2 e2702 [±81.07 J/mole]/RT
Bath gas:   CH4
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
273 6.28E0
275 6.23E0
298 5.68E0