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Accessibility information
Author(s):   Wallington, T.J.; Dagaut, P.; Liu, R.; Kurylo, M.J.
Title:   The gas phase reactons of hydroxyl radicals with a series of esters over the temperature range 240-440 K
Journal:   Int. J. Chem. Kinet.
Volume:   20
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988WAL/DAG177

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1988WAL/DAG177   CH3C(O)OCH3 + ·OH → Products  296 - 440   8.30E-13       2162   3.47E-13  2
  1988WAL/DAG177   C2H5C(O)OC2H5 + ·OH → Products  296   2.14E-12              2
  1988WAL/DAG177   CH3COOCH(CH3)C2H5 + ·OH → Products  296   5.65E-12              2
  1988WAL/DAG177   n-C3H7C(O)OC2H5 + ·OH → Other Products + H2O  296   4.95E-12              2
  1988WAL/DAG177   n-C3H7C(O)OCH2CH2CH3 + ·OH → Products  296   7.42E-12              2
  1988WAL/DAG177   C2H5C(O)OCH2CH2CH3 + ·OH → Products  296   4.02E-12              2
  1988WAL/DAG177   HC(O)OCH3 + ·OH → Products  296   2.27E-13              2
  1988WAL/DAG177   CH3COOCH(CH3)2 + ·OH → Other Products + H2O  296   3.72E-12              2
  1988WAL/DAG177   n-C3H7C(O)O(CH2)3CH3 + ·OH → Products  296   1.06E-11              2
  1988WAL/DAG177   CH3COOCH2CH2CH3 + ·OH → Other Products + H2O  296   3.45E-12              2
  1988WAL/DAG177   HC(O)OC2H5 + ·OH → Products  296   1.02E-12              2
  1988WAL/DAG177   HCOOCH2CH2CH3 + ·OH → Products  296   2.37E-12              2
  1988WAL/DAG177   CH3COO(CH2)3CH3 + ·OH → Other Products + H2O  296   4.15E-12              2
  1988WAL/DAG177   CH3C(O)OC2H5 + ·OH → Products  296 - 440   2.31E-12       1089   1.49E-12  2
  1988WAL/DAG177   CF3C(O)OCH3 + ·OH → Products  240 - 440   3.01E-13       4257   5.39E-14  2
  1988WAL/DAG177   C2H5C(O)OCH3 + ·OH → Products  296   1.03E-12              2
  1988WAL/DAG177   HCOO(CH2)3CH3 + ·OH → Products  296   3.12E-12              2
  1988WAL/DAG177   Methyl butanoate + ·OH → Products  296   3.04E-12              2

Search returned 18 records.