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Author(s):   Wallington, T.J.; Dagaut, P.; Liu, R.; Kurylo, M.J.
Title:   Gas-phase reactions of hydroxyl radicals with the fuel additives methyl tert-butyl ether and tert-butyl alcohol over the temperature range 240-440 K
Journal:   Environ. Sci. Technol.
Volume:   22
Year:   1988
Reference type:   Journal article
Squib:   1988WAL/DAG842

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1988WAL/DAG842   tert-C4H9OH + ·OH → Other Products + H2O  240 - 440   3.30E-12       2577   1.17E-12  2
  1988WAL/DAG842   tert-C4H9OCH3 + ·OH → Other Products + H2O  240 - 440   5.10E-12       1289   3.03E-12  2

Search returned 2 records.