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Author(s):   Wallington, T.J.; Liu, R.; Dagaut, P.; Kurylo, M.J.
Title:   The gas phase reactions of hydroxyl radicals with a series of aliphatic ethers over the temperature range 240-440 K
Journal:   Int. J. Chem. Kinet.
Volume:   20
Year:   1988
Reference type:   Journal article
Squib:   1988WAL/LIU41

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1988WAL/LIU41   (C2H5)2O + ·OH → Other Products + H2O  240 - 440   5.60E-12       -2245   1.38E-11  2
  1988WAL/LIU41   Oxirane + ·OHH2O + Oxiranyl  298   9.51E-14           9.51E-14  2
  1988WAL/LIU41   Methyloxirane + ·OH → Other Products + H2O  298   4.95E-13           4.95E-13  2
  1988WAL/LIU41   Tetrahydrofuran + ·OH → Products  298   1.78E-11           1.78E-11  2
  1988WAL/LIU41   (n-C3H7)2O + ·OH → Other Products + H2O  240 - 440   1.10E-11       -1247   1.82E-11  2
  1988WAL/LIU41   (CH3)2O + ·OHH2O + CH3OCH2  240 - 440   6.71E-12       2494   2.45E-12  2
  1988WAL/LIU41   (n-C4H9)2O + ·OH → Other Products + H2O  298   2.77E-11           2.77E-11  2
  1988WAL/LIU41   (n-C5H11)2O + ·OH → Other Products + H2O  298   3.47E-11           3.47E-11  2

Search returned 8 records.