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Accessibility information
Author(s):   Al-Awadi, N.A.; Al-Bashir, R.F.; El-Dusouqui, O.M.E.
Title:   Gas-phase pyrolytic reactions. Rate data for pyrolysis of N-t-butylthio-acetamide and N-acetylthioacetamide: role of polarity of transition state and γ-carbonyl group protophilicity
Journal:   J. Chem. Soc. Perkin Trans. 2
Page(s):   579 - 581
Year:   1989
Reference type:   Journal article
Squib:   1989ALA/ALB579-581

Reaction:   CH3C(O)NHC(O)CH3CH3CONH2 + H2C=C=O
Reaction order:   1
Temperature:   565 - 615 K
Rate expression:   7.24x1011 [s-1] e-151323 [±3026 J/mole]/RT
Uncertainty:   2.56999993
Bath gas:   CH3C(O)NHC(O)CH3
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
565 7.41E-3
575 1.30E-2
600 4.85E-2
615 1.02E-1