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Author(s):   Batt, L.; Hisham, M.W.M.; Mackay, M.
Title:   Decomposition of the t-butoxy radical: II. Studies over the temperature range 303-393 K
Journal:   Int. J. Chem. Kinet.
Volume:   21
Page(s):   535 - 546
Year:   1989
Reference type:   Journal article
Squib:   1989BAT/HIS535-546

Reaction:   (CH3)3CO → (CH3)2CO + ·CH3
Reaction order:   1
Temperature:   303 - 393 K
Pressure:  1.33E-3 - 1.20 bar
Rate expression:   1.1x1014 [s-1] e-62525 [±625 J/mole]/RT
Uncertainty:   2.33999991
Bath gas:   CF4
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
303 1.83E3
325 9.83E3
350 5.13E4
375 2.15E5
393 5.39E5