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Author(s):   Canosa-Mas, C.E.; Smith, S.J.; Toby, S.; Wayne, R.P.
Title:   Laboratory studies of the reactions of the nitrate radical with chloroform, methanol, hydrogen chloride and hydrogen bromide
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   85
Page(s):   709 - 725
Year:   1989
Reference type:   Journal article
Squib:   1989CAN/SMI709-725

Reaction:   CH3OH + NO3(·)CH2OH + HNO3
Reaction order:   2
Temperature:   294 - 473 K
Pressure:  2.40E-3 - 6.93E-3 bar
Rate expression:   1.25x10-12 [cm3/molecule s] e-21285 [±1921 J/mole]/RT
Uncertainty:   1.92999995
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
294 2.07E-16
300 2.46E-16
325 4.74E-16
350 8.33E-16
375 1.36E-15
400 2.08E-15
425 3.03E-15
450 4.23E-15
473 5.58E-15