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Accessibility information
Author(s):   Croce de Cobos, A.E.; Cobos, C.J.; Castellano, E.
Title:   Pressure and temperature dependence of the reaction F + FSO3 + M →’ FSO2OF + M
Journal:   J. Phys. Chem.
Volume:   93
Page(s):   274 - 278
Year:   1989
Reference type:   Journal article
Squib:   1989CRO/COB274-278

Reaction:   ·F + FSO3 → F2SO3
Reaction order:   2
Temperature:   298 - 378 K
Pressure:  6.67E-3 - 0.80 bar
Rate expression:   7.21x10-11 [±7.97x10-12 cm3/molecule s] (T/298 K)0.23
Bath gas:   CF4
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 7.21E-11
300 7.22E-11
325 7.35E-11
350 7.48E-11
375 7.60E-11
378 7.61E-11