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Accessibility information
Author(s):   Loser, U.; Scherzer, K.; Weber, K.
Title:   Abschatzung kinetischer daten fur H-transferreaktionen mit hilfe der, bond strength-bond length (BSBL) "Methode"
Journal:   Z. Phys. Chem. (Leipzig)
Volume:   270
Page(s):   237 - 245
Year:   1989
Reference type:   Journal article
Squib:   1989LOS/SCH237-245

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1989LOS/SCH237-245   (CH3)2CO + ·CH2CH=CH2CH3CH=CH2 + CH3C(O)CH2(·)  790 - 810   1.18E-12       6.90E04      2
  1989LOS/SCH237-245   CH4 + ·CH2CH=CH2CH3CH=CH2 + ·CH3  790 - 810   8.14E-13       9.40E04      2
  1989LOS/SCH237-245   C2H6 + ·CH2CH=CH2CH3CH=CH2 + ·C2H5  790 - 810   1.20E-12       6.86E04      2
  1989LOS/SCH237-245   C3H8 + ·CH2CH=CH2CH3CH=CH2 + iso-C3H7  790 - 810   5.76E-13       5.62E04      2
  1989LOS/SCH237-245   C3H8 + ·CH2CH=CH2CH3CH=CH2 + n-C3H7  790 - 810   1.20E-12       6.92E04      2
  1989LOS/SCH237-245   CH3CHO + ·CH2CH=CH2CH3CH=CH2 + CH3CO  790 - 810   6.31E-13       3.02E04      2
  1989LOS/SCH237-245   CH3CH=CH2 + n-C3H7C3H8 + ·CH2CH=CH2  490 - 510   1.32E-13       1.85E04      2
  1989LOS/SCH237-245   CH3CH=CH2 + ·CH3CH4 + ·CH2CH=CH2  490 - 510   1.78E-13       2.23E04      2
  1989LOS/SCH237-245   CH3CH=CH2 + CH3C(O)CH2(·)(CH3)2CO + ·CH2CH=CH2  490 - 510   4.30E-14       1.89E04      2
  1989LOS/SCH237-245   CH3CH=CH2 + CH3COCH3CHO + ·CH2CH=CH2  490 - 510   2.57E-13       2.92E04      2
  1989LOS/SCH237-245   CH3CH=CH2 + H2 + ·CH2CH=CH2  490 - 510   1.07E-12       1.86E04      2
  1989LOS/SCH237-245   CH3CH=CH2 + ·C2H5C2H6 + ·CH2CH=CH2  490 - 510   1.15E-13       2.17E04      2
  1989LOS/SCH237-245   H2 + ·CH2CH=CH2CH3CH=CH2 +   790 - 810   1.69E-12       1.06E05      2

Search returned 13 records.