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Author(s):   Muller-Markgraf, W.; Rossi, M.J.; Golden, D.M.
Title:   Rate constants for the reactions t-C4H9 + DX →’ i-C4H9D + X (X = Br, I), 295 < T (K) < 384: Heat of formation of the tert-butyl radical
Journal:   J. Am. Chem. Soc.
Volume:   111
Page(s):   956 - 962
Year:   1989
Reference type:   Journal article
Squib:   1989MUL/ROS956-962

Reaction:   tert-C4H9 + DI(CH3)3CD + I
Reaction order:   2
Temperature:   295 - 384 K
Rate expression:   1.88x10-12 [±7.8x10-13 cm3/molecule s] e-4124 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
295 3.49E-13
300 3.59E-13
325 4.08E-13
350 4.55E-13
375 5.00E-13
384 5.16E-13