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Accessibility information
Author(s):   Staker, W.S.; King, K.D.
Title:   Collisional energy transfer in the three-channel thermal decomposition of 1-chloro-2,2,3,3-tetrafluorocyclobutane
Journal:   J. Phys. Chem.
Volume:   93
Page(s):   1805 - 1812
Year:   1989
Reference type:   Journal article
Squib:   1989STA/KIN1805-1812

Reaction:   Cyclobutane, 1-chloro-2,2,3,3-tetrafluoro-CH2=CHCl + C2F4
Reaction order:   1
Temperature:   915 - 1220 K
Rate expression:   2.0x1015 [s-1] e-286849 [±8647 J/mole]/RT
Uncertainty:   2.0
Bath gas:   Ne
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
915 8.43E-2
925 1.27E-1
950 3.38E-1
975 8.58E-1
1000 2.08E0
1025 4.82E0
1050 1.07E1
1075 2.31E1
1100 4.79E1
1125 9.61E1
1150 1.87E2
1175 3.54E2
1200 6.53E2
1220 1.05E3