Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Staker, W.S.; King, K.D.
Title:   Collisional energy transfer in the three-channel thermal decomposition of 1-chloro-2,2,3,3-tetrafluorocyclobutane
Journal:   J. Phys. Chem.
Volume:   93
Page(s):   1805 - 1812
Year:   1989
Reference type:   Journal article
Squib:   1989STA/KIN1805-1812

Reaction:   Cyclobutane, 1-chloro-2,2,3,3-tetrafluoro-CH2=CHCl + C2F4
Reaction order:   1
Temperature:   915 - 1220 K
Rate expression:   2.0x1015 [s-1] e-286849 [±8647 J/mole]/RT
Uncertainty:   2.0
Bath gas:   Ne
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
915 8.43E-2
925 1.27E-1
950 3.38E-1
975 8.58E-1
1000 2.08E0
1025 4.82E0
1050 1.07E1
1075 2.31E1
1100 4.79E1
1125 9.61E1
1150 1.87E2
1175 3.54E2
1200 6.53E2
1220 1.05E3