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Accessibility information
Author(s):   Staker, W.S.; King, K.D.
Title:   Collisional energy transfer in the three-channel thermal decomposition of 1-chloro-2,2,3,3-tetrafluorocyclobutane
Journal:   J. Phys. Chem.
Volume:   93
Page(s):   1805 - 1812
Year:   1989
Reference type:   Journal article
Squib:   1989STA/KIN1805-1812

Reaction:   Cyclobutane, 1-chloro-2,2,3,3-tetrafluoro-CF2CHCHCF2 + HCl
Reaction order:   1
Temperature:   915 - 1220 K
Rate expression:   1.58x1013 [s-1] e-271052 [±8132 J/mole]/RT
Uncertainty:   2.0
Bath gas:   Ne
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
915 5.31E-3
925 7.81E-3
950 1.97E-2
975 4.76E-2
1000 1.10E-1
1025 2.43E-1
1050 5.19E-1
1075 1.07E0
1100 2.13E0
1125 4.11E0
1150 7.72E0
1175 1.41E1
1200 2.51E1
1220 3.92E1