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Accessibility information
Author(s):   Abadzhev, S.S.; Dzikh, I.P.; Shevchuk, V.U.
Title:   Kinetic features of joint pyrolysis of methyl chloride and methane
Journal:   Kinet. Catal.
Volume:   30
Page(s):   893 - 897
Year:   1990
Reference type:   Journal article
Squib:   1990ABA/DZI893-897

Reaction:   CH3Cl·CH3 + ·Cl
Reaction order:   1
Temperature:   1220 - 1370 K
Pressure:  1.01 bar
Rate expression:   4.68x1012 [s-1] e-297658 [J/mole]/RT
Uncertainty:   2.08999991
Bath gas:   CH4
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1220 8.44E-1
1225 9.51E-1
1250 1.71E0
1275 2.99E0
1300 5.13E0
1325 8.63E0
1350 1.42E1
1370 2.10E1