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Accessibility information
Author(s):   Anastasi, C.; Hancock, D.U.
Title:   Reaction of CH3 radicals with methanol in the range 525 ≤ T/K ≤ 603
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   86
Page(s):   2553 - 2555
Year:   1990
Reference type:   Journal article
Squib:   1990ANA/HAN2553-2555

Reaction:   CH3OH + ·CH3 → Other Products + CH4
Reaction order:   2
Temperature:   525 - 603 K
Rate expression:   1.3x10-11 [cm3/molecule s] e-55291 [±3317 J/mole]/RT
Uncertainty:   2.0
Bath gas:   CH3OH
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Direct photolysis
Analytical technique:   Vis-UV emission

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
525 4.10E-17
550 7.29E-17
575 1.23E-16
600 2.00E-16
603 2.11E-16