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Title: Reaction of CH3 radicals with methanol in the range 525 ⤠T/K ⤠603
Journal: J. Chem. Soc. Faraday Trans.
Volume: 86
Page(s): 2553 - 2555
Year: 1990
Reference type: Journal article
Squib: 1990ANA/HAN2553-2555
Reaction:
CH3OH + ·CH3 → Other Products + CH4
Reaction order:
2
Temperature:
525 - 603
K
Rate expression:
1.3x10-11 [cm3/molecule s] e-55291 [±3317 J/mole]/RT
Uncertainty:
2.0
Bath gas:
CH3OH
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Direct photolysis
Analytical technique:
Vis-UV emission
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 525 | 4.10E-17 |
| 550 | 7.29E-17 |
| 575 | 1.23E-16 |
| 600 | 2.00E-16 |
| 603 | 2.11E-16 |