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Accessibility information
Author(s):   Brand, U.; Hippler, H.; Lindemann, L.; Troe, J.
Title:   C-C and C-H bond splits of laser-excited aromatic molecules. 1. Specific and thermally averaged rate constants
Journal:   J. Phys. Chem.
Volume:   94
Page(s):   6305 - 6316
Year:   1990
Reference type:   Journal article
Squib:   1990BRA/HIP6305-6316

Reaction:   EthylbenzeneBenzyl + ·CH3
Reaction order:   1
Temperature:   900 - 1700 K
Rate expression:   2.09x1016 [s-1] e-322602 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
900 3.96E-3
950 3.83E-2
1000 2.95E-1
1050 1.87E0
1100 1.00E1
1150 4.65E1
1200 1.90E2
1250 6.91E2
1300 2.28E3
1350 6.89E3
1400 1.92E4
1450 5.00E4
1500 1.22E5
1550 2.81E5
1600 6.14E5
1650 1.28E6
1700 2.56E6