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Accessibility information
Author(s):   Brand, U.; Hippler, H.; Lindemann, L.; Troe, J.
Title:   C-C and C-H bond splits of laser-excited aromatic molecules. 1. Specific and thermally averaged rate constants
Journal:   J. Phys. Chem.
Volume:   94
Page(s):   6305 - 6316
Year:   1990
Reference type:   Journal article
Squib:   1990BRA/HIP6305-6316

Reaction:   1,3-Dimethylbenzene3-Methylbenzyl +
Reaction order:   1
Temperature:   1100 - 1900 K
Rate expression:   1.95x1016 [s-1] e-370825 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 4.80E-2
1150 2.80E-1
1200 1.41E0
1250 6.23E0
1300 2.46E1
1350 8.75E1
1400 2.85E2
1450 8.55E2
1500 2.38E3
1550 6.22E3
1600 1.53E4
1650 3.56E4
1700 7.87E4
1750 1.67E5
1800 3.38E5
1850 6.61E5
1900 1.25E6