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Accessibility information
Author(s):   Hippler, H.; Reihs, C.; Troe, J.
Title:   Elementary steps in the pyrolysis of toluene and benzyl radicals
Journal:   Z. Phys. Chem. (Neue Folge)
Volume:   167
Page(s):   1 - 16
Year:   1990
Reference type:   Journal article
Squib:   1990HIP/REI1-16

Reaction:   Toluene → Products
Reaction order:   1
Temperature:   1200 - 1500 K
Pressure:  7.47E-2 - 4.96 bar
Rate expression:   1.0x1015 [s-1] e-360017 [±21618 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1200 2.13E-1
1225 4.46E-1
1250 9.04E-1
1275 1.78E0
1300 3.42E0
1325 6.42E0
1350 1.18E1
1375 2.11E1
1400 3.70E1
1425 6.36E1
1450 1.07E2
1475 1.78E2
1500 2.91E2