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Accessibility information
Author(s):   Hippler, H.; Reihs, C.; Troe, J.
Title:   Elementary steps in the pyrolysis of toluene and benzyl radicals
Journal:   Z. Phys. Chem. (Neue Folge)
Volume:   167
Page(s):   1 - 16
Year:   1990
Reference type:   Journal article
Squib:   1990HIP/REI1-16

Reaction:   TolueneBenzyl +
Reaction order:   1
Temperature:   1100 - 1900 K
Rate expression:   6.31x1015 [s-1] e-378308 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 6.86E-3
1150 4.14E-2
1200 2.15E-1
1250 9.81E-1
1300 3.98E0
1350 1.45E1
1400 4.85E1
1450 1.49E2
1500 4.23E2
1550 1.13E3
1600 2.82E3
1650 6.67E3
1700 1.50E4
1750 3.22E4
1800 6.64E4
1850 1.31E5
1900 2.51E5