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Author(s):   Lightfoot, P.D.; Veyret, B.; Lesclaux, R.
Title:   Flash photolysis study of the CH3O2 + HO2 reaction between 248 and 573 K
Journal:   J. Phys. Chem.
Volume:   94
Page(s):   708 - 714
Year:   1990
Reference type:   Journal article
Squib:   1990LIG/VEY708-714

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1990LIG/VEY708-714   CH3OH + Cl(·)CH2OH + HCl  248 - 573   5.30E-11           5.30E-11  2
  1990LIG/VEY708-714   CH3OH + Cl(·)CH2OH + HCl  248 - 573   4.58       -1.16E04   503  2
  Reference reaction:  CH4 + Cl·CH3 + HCl 2
  1990LIG/VEY708-714   CH3O2· + HO2 → Products  248 - 573   4.40E-13       -6485   6.03E-12  2
    1990LIG/VEY708-714   HO2 + HO2H2O2 + O2                      

Search returned 4 records.