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Author(s):   Liu, R.; Huie, R.E.; Kurylo, M.J.
Title:   Rate constants for the reactions of the OH radical with some hydrochlorofluorocarbons over the temperature range 270-400 K
Journal:   J. Phys. Chem.
Volume:   94
Page(s):   3247 - 3249
Year:   1990
Reference type:   Journal article
Squib:   1990LIU/HUI3247-3249

Reaction:   CF3CHCl2 + ·OHH2O + CF3CCl2
Reaction order:   2
Temperature:   220 - 400 K
Pressure:  4.67E-2 bar
Rate expression:   1.1x10-12 [±1.99x10-13 cm3/molecule s] e-8647 [±1122 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
220 9.73E-15
225 1.08E-14
250 1.72E-14
275 2.50E-14
300 3.43E-14
325 4.48E-14
350 5.63E-14
375 6.87E-14
400 8.16E-14