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Author(s):   Wiberg, K.B.; Caringi, J.J.; Matturro, M.G.
Title:   Kinetics of the thermolysis of [n.2.2]propellanes and related compounds. Mechanism of the thermolysis of bicyclo[2.2.0]hexanes
Journal:   J. Am. Chem. Soc.
Volume:   112
Page(s):   5854 - 5861
Year:   1990
Reference type:   Journal article
Squib:   1990WIB/CAR5854-5861

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1990WIB/CAR5854-5861   Pentalene 1,2,3,4,5,6-hexahydro- → Other Products + 1,2-Dimethylbenzene  723   1.30E-05              1
  1990WIB/CAR5854-5861   Cyclooctane,1,5-bis(methylene)- → Other Products + 1,2-Dimethylbenzene  588 - 743   1.00E16       2.52E05      1
  1990WIB/CAR5854-5861   Cyclooctane,1,5-bis(methylene)- → [3.3.2]Propellane  688 - 733   2.51E09       1.70E05      1
  1990WIB/CAR5854-5861   Tricyclo[,5]octaneCyclohexane, 1,3-bis(methylene)-  592 - 673   6.31E15       2.26E05      1
  1990WIB/CAR5854-5861   [3.3.2]Propellane → Other Products + Pentalene 1,2,3,4,5,6-hexahydro-  730 - 743   1.26E14       2.54E05      1
  1990WIB/CAR5854-5861   [3.3.2]Propellane → Cyclooctane,1,5-bis(methylene)-  723   2.10E-05              1
  1990WIB/CAR5854-5861   Tetracyclo[,50.2,6]undec-3-ene → Bicyclo[4.2.1]non-7-ene,2,5-bis(methylene)-  523 - 582   1.58E14       1.73E05      1
  1990WIB/CAR5854-5861   Tetracyclo[,501,6]undecane → Bicyclo[4.2.1]nonane, 2,5-bis(methylene)-  528 - 584   1.00E15       1.85E05      1
  1990WIB/CAR5854-5861   Tricyclo[,6]decane → Cyclooctane, 1,4-bis(methylene)-  577 - 640   5.01E12       1.71E05      1
  1990WIB/CAR5854-5861   Tricyclo[,6]nonane → Products  693 - 745   1.00E16       2.53E05      1
  1990WIB/CAR5854-5861   Tricyclo[,6]dec-3-ene → Cyclooctene, 4,7-bis(methylene)-  598 - 668   1.00E14       1.94E05      1

Search returned 11 records.