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Accessibility information
Author(s):   Atkinson, R.
Title:   Kinetics and mechanisms of the gas-phase reactions of the NO3 radical with organic compounds
Journal:   J. Phys. Chem. Ref. Data
Volume:   20
Page(s):   459 - 507
Year:   1991
Reference type:   Journal article
Squib:   1991ATK459-507

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1991ATK459-507   CH2O + NO3HCO + HNO3  298   5.80E-16           5.80E-16  2
  1991ATK459-507   CH3OH + NO3(·)CH2OH + HNO3  298   9.51E-18           9.51E-18  2
  1991ATK459-507   Benzene + NO3 → Products  298   <3.01E-17           3.01E-17  2
  1991ATK459-507   CH4 + NO3 → Products  298   <1.00E-18           1.00E-18  2
  1991ATK459-507   C2H4 + NO3 → Products  295 - 523   5.43E-12       2.53E04   2.02E-16  2
  1991ATK459-507   C2H2 + NO3 → Products  298   <5.00E-17           5.00E-17  2
  1991ATK459-507   CH3SH + NO3 → Products  254 - 367   9.30E-13           9.30E-13  2
  1991ATK459-507   CH3CCH + NO3 → Products  295 - 473   1.63E-11       2.77E04   2.29E-16  2
  1991ATK459-507   CH2=CHCl + NO3 → Products  298   4.30E-16           4.30E-16  2
  1991ATK459-507   CH3CN + NO3 → Products  298   <5.00E-19           5.00E-19  2
  1991ATK459-507   CH3CHO + NO3CH3CO + HNO3  264 - 374   1.44E-12       1.55E04   2.80E-15  2
  1991ATK459-507   C2H5SH + NO3 → Products  297   1.21E-12              2
  1991ATK459-507   (CH3)2S + NO3HNO3 + CH3SCH2  256 - 376   1.88E-13       -4315   1.07E-12  2
  1991ATK459-507   iso-C4H10 + NO3 → Products  296   9.80E-17              2
  1991ATK459-507   CH2=CCl2 + NO3 → Products  298   1.23E-15           1.23E-15  2
  1991ATK459-507   (CH3)4Si + NO3 → Products  297   <5.99E-17              2
  1991ATK459-507   CH2=C(CH3)CH=CH2 + NO3 → Products  251 - 381   3.02E-12       3708   6.77E-13  2
  1991ATK459-507   C2HCl3 + NO3 → Products  298   2.81E-16           2.81E-16  2
  1991ATK459-507   (CH3)2CHCH(CH3)2 + NO3 → Products  296   4.07E-16              2
  1991ATK459-507   Camphene + NO3 → Products  296   6.56E-13              2
  1991ATK459-507   alpha-pinene + NO3 → Products  261 - 384   1.19E-12       -4074   6.16E-12  2
  1991ATK459-507   Acenaphthylene, 1,2-dihydro- + N2O5 → Products  296   1.65E-27              3
  1991ATK459-507   Acenaphthylene, 1,2-dihydro- + NO3 → Products  296   4.60E-13              2
  1991ATK459-507   1-Nitronaphthalene + N2O5 → Products  298   3.03E-29           3.03E-29  3
  1991ATK459-507   1-Nitronaphthalene + NO3 → Products  298   <7.21E-15           7.21E-15  2
  1991ATK459-507   1-Methylnaphthalene + N2O5 → Products  298   7.69E-28           7.69E-28  3
  1991ATK459-507   Naphthalene + N2O5 → Products  272 - 298   3.92E-34       -3.40E04      3
  1991ATK459-507   2-Methylnaphthalene + N2O5 → Products  298   1.08E-27           1.08E-27  3
  1991ATK459-507   Biphenyl + N2O5 → Products  298   <5.02E-30           5.02E-30  3
  1991ATK459-507   1,2-Dimethylbenzene + NO3 → Products  298   3.77E-16           3.77E-16  2
  1991ATK459-507   2-Methylphenol + NO3 → Products  298   1.56E-11           1.56E-11  2
  1991ATK459-507   1,2,4-Trimethylbenzene + NO3 → Products  294   1.81E-15              2
  1991ATK459-507   γ-Terpinene + NO3 → Products  294   2.94E-11              2
  1991ATK459-507   α-Terpinene + NO3 → Products  294   1.83E-10              2
  1991ATK459-507   p-Cimene + NO3 → Products  295   1.00E-15              2
  1991ATK459-507   Ethylbenzene + NO3 → Products  298   <5.71E-16           5.71E-16  2
  1991ATK459-507   Styrene + NO3 → Products  296   1.51E-13              2
  1991ATK459-507   C6H5CH2Cl + NO3 → Products  298   <5.71E-16           5.71E-16  2
  1991ATK459-507   Benzaldehyde + NO3 → Products  204   2.54E-15              2
  1991ATK459-507   Methoxybenzene + NO3 → Products  294   9.45E-17              2
  1991ATK459-507   1,4-Dimethylbenzene + NO3 → Products  298   4.53E-16           4.53E-16  2
  1991ATK459-507   4-Methylphenol + NO3 → Products  298   1.66E-11           1.66E-11  2
  1991ATK459-507   Benzene, 1,4-Dichloro- + NO3 → Products  298   <3.40E-17           3.40E-17  2
  1991ATK459-507   1-C4H10 + NO3 → Products  296   6.59E-17              2
  1991ATK459-507   1-C4H8 + NO3 → Products  298   1.25E-14           1.25E-14  2
  1991ATK459-507   1,3-Butadiene + NO3 → Products  298   1.00E-13           1.00E-13  2
  1991ATK459-507   CH2=CHCHO + NO3 → Products  298   1.11E-15           1.11E-15  2
  1991ATK459-507   CH2=CHCH2Cl + NO3 → Products  298   5.35E-16           5.35E-16  2
  1991ATK459-507   ((CH3)3Si)2O + NO3 → Products  297   <5.99E-17              2
  1991ATK459-507   1,3-Dimethylbenzene + NO3 → Products  298   2.32E-16           2.32E-16  2
  1991ATK459-507   3-Methylphenol + NO3 → Products  298   1.20E-11           1.20E-11  2
  1991ATK459-507   1,3,5-Trimethylbenzene + NO3 → Products  298   8.00E-16           8.00E-16  2
  1991ATK459-507   Toluene + NO3 → Products  298   6.79E-17           6.79E-17  2
  1991ATK459-507   Phenol + NO3 → Products  298   3.64E-12           3.64E-12  2
  1991ATK459-507   n-C5H12 + NO3 → Products  296   8.10E-17              2
  1991ATK459-507   Pyrrole + NO3 → Products  295   4.60E-11              2
  1991ATK459-507   Tetrahydrofuran + NO3 → Products  296   4.90E-15              2
  1991ATK459-507   Furan + NO3 → Products  295   1.44E-12              2
  1991ATK459-507   Thiophene + NO3 → Products  272 - 296   3.94E-14              2
  1991ATK459-507   1-C6H14 + NO3 → Products  296   1.05E-16              2
  1991ATK459-507   Cyclohexane + NO3 → Products  296   1.35E-16              2
  1991ATK459-507   Cyclohexene + NO3 → Products  295   5.28E-13              2
  1991ATK459-507   n-C8H18 + NO3 → Products  296   1.83E-16              2
  1991ATK459-507   n-C9H20 + NO3 → Products  296   2.41E-16              2
  1991ATK459-507   CH3CH=CH2 + NO3 → Products  298   9.45E-15           9.45E-15  2
  1991ATK459-507   iso-C4H8 + NO3 → Products  298   3.32E-13           3.32E-13  2
  1991ATK459-507   1,2,3,4-Tetrahydronaphthalene + NO3 → Products  298   1.11E-14           1.11E-14  2
  1991ATK459-507   2,5-Norbornadiene + NO3 → Products  298   1.02E-12           1.02E-12  2
  1991ATK459-507   Myrcene + NO3 → Products  294   1.06E-11              2
  1991ATK459-507   C2Cl4 + NO3 → Products  298   <5.20E-17           5.20E-17  2
  1991ATK459-507   beta-pinene + NO3 → Products  298   2.51E-12           2.51E-12  2
  1991ATK459-507   Pyrene + N2O5 → Products  296   1.60E-27              3
  1991ATK459-507   1,4-Naphthalenedione + N2O5 → Products  298   <8.49E-30           8.49E-30  3
  1991ATK459-507   1,4-Naphthalenedione + NO3 → Products  298   <9.51E-16           9.51E-16  2
  1991ATK459-507   Cyclopentene + NO3 → Products  298   4.63E-13           4.63E-13  2
  1991ATK459-507   1-C7H16 + NO3 → Products  296   1.37E-16              2
  1991ATK459-507   (CH3O)3PS + NO3 → Products  298   <1.60E-14           1.60E-14  2
  1991ATK459-507   Phosphorothioic acid, O,O,S-trimethyl ester + NO3 → Products  298   <1.10E-15           1.10E-15  2
  1991ATK459-507   (Z)-CHCl=CHCl + NO3 → Products  298   1.39E-16           1.39E-16  2
  1991ATK459-507   (E)-CHCl=CHCl + NO3 → Products  298   1.07E-16           1.07E-16  2
  1991ATK459-507   Fluoranthene + N2O5 → Products  296   5.10E-28              3
  1991ATK459-507   Acenaphthylene + NO3 → Products  296   5.45E-12              2
  1991ATK459-507   Azulene + NO3 → Products  298   3.89E-10           3.89E-10  2
  1991ATK459-507   1,4-Benzodioxin, 2,3-dihydro- + NO3 → Products  298   5.99E-16           5.99E-16  2
  1991ATK459-507   Benzofuran, 2,3-dihydro + NO3 → Products  298   1.15E-13           1.15E-13  2
  1991ATK459-507   Bicyclo[2.2.1]hept-2-ene + NO3 → Products  298   2.47E-13           2.47E-13  2
  1991ATK459-507   (CH3)2C=CHCH3 + NO3 → Products  298   9.38E-12           9.38E-12  2
  1991ATK459-507   CH2=C(CH3)C(CH3)=CH2 + NO3 → Products  298   2.09E-12           2.09E-12  2
  1991ATK459-507   1,2,3-Trimethylbenzene + NO3 → Products  294   1.86E-15              2
  1991ATK459-507   Cyclopentasiloxane, decamethyl- + NO3 → Products  297   <2.09E-16              2
  1991ATK459-507   Cyclotrisiloxane, hexamethyl- + NO3 → Products  297   <1.40E-16              2
  1991ATK459-507   1,3,5-Cycloheptatriene + NO3 → Products  298   1.19E-12           1.19E-12  2
  1991ATK459-507   2-Carene + NO3 → Products  295   1.88E-11              2
  1991ATK459-507   Cyclotetrasiloxane, octamethyl- + NO3 → Products  297   <1.40E-16              2
  1991ATK459-507   (CH3)2C=C(CH3)2 + NO3 → Products  298   5.71E-11           5.71E-11  2
  1991ATK459-507   Naphthalene, 2,3-dimethyl- + N2O5 → Products  298   1.55E-27           1.55E-27  3
  1991ATK459-507   2-Nitronaphthalene + N2O5 → Products  298   2.74E-29           2.74E-29  3
  1991ATK459-507   2-Nitronaphthalene + NO3 → Products  298   <7.31E-15           7.31E-15  2
  1991ATK459-507   Terpinolene + NO3 → Products  295   9.66E-11              2
  1991ATK459-507   (Z)-2-C4H8 + NO3 → Products  298   3.50E-13           3.50E-13  2
  1991ATK459-507   1,3-Cyclohexadiene + NO3 → Products  298   1.16E-11           1.16E-11  2
  1991ATK459-507   (CH3)2Se + NO3 → Products  296   1.40E-11              2
  1991ATK459-507   (CH3O)2P(O)N(CH3)2 + NO3 → Products  296   <3.60E-14              2
  1991ATK459-507   (E)-2-C4H8 + NO3 → Products  204 - 378   1.08E-13   2.00   -3176   3.91E-13  2
  1991ATK459-507   (CH3S)2 + NO3 → Products  300 - 380   7.01E-13              2
  1991ATK459-507   1,4-Cyclohexadiene + NO3 → Products  298   6.59E-13           6.59E-13  2
  1991ATK459-507   (Z)-Cycloheptene + NO3 → Products  298   4.85E-13           4.85E-13  2
  1991ATK459-507   Naphthalene, 2-methyl-1-nitro- + N2O5 → Products  298   2.74E-29           2.74E-29  3
  1991ATK459-507   Bicyclo[2.2.2]oct-2-ene + NO3 → Products  298   1.45E-13           1.45E-13  2
  1991ATK459-507   C6H5CD3 + NO3 → Products  296   3.84E-17              2
  1991ATK459-507   Naphthalene d8 + N2O5 → Products  296   4.77E-28              3
  1991ATK459-507   C6D5CD3 + NO3 → Products  296   3.44E-17              2
  1991ATK459-507   (CH3O)2P(S)Cl + NO3 → Products  296   <2.81E-14              2
  1991ATK459-507   (CH3O)2P(S)SCH3 + NO3 → Products  298   <2.81E-14           2.81E-14  2
  1991ATK459-507   1,3,6-Octatriene, 3,7-dimethyl-,(Z)- + NO3 → Products  294   2.23E-11              2
  1991ATK459-507   Sabinene + NO3 → Products  296   1.01E-11              2
  1991ATK459-507   trans-Ocimene + NO3 → Products  294   2.23E-11              2
  1991ATK459-507   1,3-Cycloheptadiene + NO3 → Products  295   6.48E-12              2
  1991ATK459-507   (E)-CH3CH=CHCHO + NO3 → Products  298   5.11E-15           5.11E-15  2
  1991ATK459-507   α-Phellandrene (R) + NO3 → Products  294   8.52E-11              2
  1991ATK459-507   d-Limonene + NO3 → Products  298   1.22E-11           1.22E-11  2
  1991ATK459-507   NO3 + 3-Carene → Products  298   9.10E-12           9.10E-12  2
  1991ATK459-507   NO3 + (CH3O)2P(S)NH2 → Products  296   4.05E-13              2
  1991ATK459-507   NO3 + (CH3S)2P(O)OCH3 → Products  298   <2.41E-15           2.41E-15  2
  1991ATK459-507   NO3 + (CH3O)2P(S)N(CH3)2 → Products  296   3.24E-14              2
  1991ATK459-507   NO3 + (CH3O)2P(S)NHCH3 → Products  296   3.11E-13              2

Search returned 126 records.