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Author(s):   Baer, S.; Hippler, H.; Rahn, R.; Siefke, M.; Seitzinger, N.; Troe, J.
Title:   Thermodynamic and kinetic properties of the reaction Cl + O2 + M = ClOO + M in the range 160-300 K and 1-1000 bar
Journal:   J. Chem. Phys.
Volume:   95
Page(s):   6463 - 6470
Year:   1991
Reference type:   Journal article
Squib:   1991BAE/HIP6463-6470

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1991BAE/HIP6463-6470   O2 + ·ClClOO  160 - 260   8.80E-34   -3.00          3
  1991BAE/HIP6463-6470   O2 + ·ClClOO  160 - 260   1.40E-33   -3.90          3
  1991BAE/HIP6463-6470   O2 + ·ClClOO  160 - 260   1.60E-33   -2.90          3
  1991BAE/HIP6463-6470   O2 + ·ClClOO  160   2.20E-32              3
  1991BAE/HIP6463-6470   Cl2 + ClOOCl2O + ClO  160 - 260   3.40E-12              2
  1991BAE/HIP6463-6470   ClOO + ClOO → Products  180 - 260   1.60E-11              2

Search returned 6 records.