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Author(s):   Baer, S.; Hippler, H.; Rahn, R.; Siefke, M.; Seitzinger, N.; Troe, J.
Title:   Thermodynamic and kinetic properties of the reaction Cl + O2 + M = ClOO + M in the range 160-300 K and 1-1000 bar
Journal:   J. Chem. Phys.
Volume:   95
Page(s):   6463 - 6470
Year:   1991
Reference type:   Journal article
Squib:   1991BAE/HIP6463-6470

Reaction:   O2 + ·ClClOO
Reaction order:   3
Temperature:   160 - 260 K
Pressure:  1.01 - 1013 bar
Rate expression:   1.6x10-33 [cm6/molecule2 s] (T/298 K)-2.90
Uncertainty:   1.20000005
Bath gas:   O2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
160 9.73E-33
175 7.50E-33
200 5.09E-33
225 3.62E-33
250 2.67E-33
260 2.38E-33