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Author(s):   Buchta, C.; Frerichs, H.; Stucken, D.; Tappe, M.; Wagner, H.G.
Title:   Investigation of the reactions of diethylether, n-dipropylether and n-dibutylether with O(3P) in the gas phase
Journal:   Z. Phys. Chem. (Munich)
Volume:   174
Page(s):   129 - 137
Year:   1991
Reference type:   Journal article
Squib:   1991BUC/FRE129-137

Reaction:   (n-C4H9)2O + → Other Products + ·OH
Reaction order:   2
Temperature:   298 - 873 K
Pressure:  2.00E-3 - 1.00E-2 bar
Rate expression:   3.32x10-11 [±6.64x10-12 cm3/molecule s] e-11807 [±2370 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.83E-13
300 2.92E-13
350 5.74E-13
400 9.54E-13
450 1.42E-12
500 1.94E-12
550 2.51E-12
600 3.11E-12
650 3.74E-12
700 4.37E-12
750 5.00E-12
800 5.63E-12
850 6.25E-12
873 6.53E-12