Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Cohen, N.; Westberg, K.R.
Title:   Chemical kinetic data sheets for high-temperature reactions. Part II
Journal:   J. Phys. Chem. Ref. Data
Volume:   20
Page(s):   1211 - 1311
Year:   1991
Reference type:   Journal article
Squib:   1991COH/WES1211-1311

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1991COH/WES1211-1311   CHCl3 + ·OH·CCl3 + H2O  250 - 2000   1.43E-13   2.80   831   1.02E-13  2
  1991COH/WES1211-1311   CH3CCl3 + ·OHH2O + CCl3CH2  250 - 2000   2.09E-12   1.10   1.34E04   9.42E-15  2
  1991COH/WES1211-1311   CH4 + ·CH3 + ·OH  298 - 2500   2.26E-12   2.20   3.18E04   6.12E-18  2
  1991COH/WES1211-1311   CH3Br + ·OHH2O + ·CH2Br  250 - 2000   2.08E-13   1.30   4157   3.88E-14  2
  1991COH/WES1211-1311   C2H6 + ·C2H5 + ·OH  1300 - 3000   4.32E-09       5.83E04      2
  1991COH/WES1211-1311   C2H6 + ·C2H5 + ·OH  298 - 1300   2.21E-15   6.50   1164   1.38E-15  2
  1991COH/WES1211-1311   CH3Cl + ·OH·CH2Cl + H2O  250 - 2000   1.40E-12   1.60   8647   4.28E-14  2
  1991COH/WES1211-1311   C3H8 + → Other Products + ·OH  298 - 2000   5.78E-13   3.50   1.06E04   7.88E-15  2
  1991COH/WES1211-1311   C3H8 + iso-C3H7 + ·OH  298 - 2000   0.27   0.10   -9728   13.44  2
  Reference reaction:  C3H8 + 1-C3H7 + ·OH 2
  1991COH/WES1211-1311   C2H5Cl + ·OH → Other Products + H2O  298 - 2000   2.92E-13   2.60   -915   4.23E-13  2
  1991COH/WES1211-1311   CH2Cl2 + ·OHCHCl2 + H2O  250 - 2000   9.07E-13   1.60   4324   1.58E-13  2
  1991COH/WES1211-1311   CH2F2 + ·OH·CHF2 + H2O  250 - 2000   7.47E-13   1.70   1.07E04   9.85E-15  2
  1991COH/WES1211-1311   iso-C4H10 + → Other Products + ·OH  298 - 2000   1.48E-13   3.90   665   1.13E-13  2
  1991COH/WES1211-1311   iso-C4H10 + tert-C4H9 + ·OH  298 - 2000   0.07   0.10   -1.93E04   158  2
  Reference reaction:  iso-C4H10 + ·OH + iso-C4H9 2
  1991COH/WES1211-1311   CH3CHCl2 + ·OH → Other Products + H2O  298 - 2000   3.17E-13   1.60   499   2.59E-13  2
  1991COH/WES1211-1311   CH3CHF2 + ·OH → Other Products + H2O  298 - 2000   3.02E-13   1.60   5155   3.77E-14  2
  1991COH/WES1211-1311   CHFCl2 + ·OH·CCl2F + H2O  250 - 2000   2.42E-13   1.70   5072   3.13E-14  2
  1991COH/WES1211-1311   CHF2Cl + ·OH·CClF2 + H2O  250 - 2000   2.31E-13   1.80   9811   4.40E-15  2
  1991COH/WES1211-1311   CHF3 + ·OH·CF3 + H2O  298 - 2000   2.69E-13   1.80   1.80E04   1.91E-16  2
  1991COH/WES1211-1311   CH3CF2Cl + ·OH → CF2ClCH2· + H2O  250 - 2000   2.97E-13   1.10   1.08E04   3.79E-15  2
  1991COH/WES1211-1311   CF3CH2Cl + ·OHH2O + CF3CHCl  250 - 2000   4.27E-13   1.70   8481   1.39E-14  2
  1991COH/WES1211-1311   CHCl2CH2Cl + ·OH → Other Products + H2O  250 - 2000   2.42E-13   1.60   -665   3.17E-13  2
  1991COH/WES1211-1311   (CH3)2CHCH(CH3)2 + → Other Products + ·OH  250 - 2000   3.09E-13   3.60   1164   1.93E-13  2
  1991COH/WES1211-1311   CH2BrCH2Br + ·OH → Other Products + H2O  298 - 2000   4.80E-13   1.70   1497   2.62E-13  2
  1991COH/WES1211-1311   1-C4H10 + → Other Products + ·OH  250 - 2000   3.49E-13   3.90   6485   2.55E-14  2
  1991COH/WES1211-1311   1-C4H10 + sec-C4H9 + ·OH  298 - 2000   0.27   0.20   -1.22E04   37.75  2
  Reference reaction:  1-C4H10 + 1-C4H9 + ·OH 2
  1991COH/WES1211-1311   n-C5H12 + → Other Products + ·OH  250 - 2000   1.66E-12   3.00   8398   5.60E-14  2
  1991COH/WES1211-1311   1-C6H14 + → Other Products + ·OH  250 - 2000   2.49E-12   2.90   8314   8.69E-14  2
  1991COH/WES1211-1311   Cyclohexane + Cyclohexyl + ·OH  298 - 2000   1.17E-11   2.60   1.03E04   1.83E-13  2
  1991COH/WES1211-1311   n-C8H18 + → Other Products + ·OH  250 - 2000   2.67E-12   2.80   6984   1.60E-13  2
  1991COH/WES1211-1311   1-C7H16 + → Other Products + ·OH  250 - 2000   2.19E-12   2.90   7317   1.14E-13  2
  1991COH/WES1211-1311   Cyclopentane + ·OH + Cyclopentyl  298 - 2000   1.30E-11   2.60   1.16E04   1.23E-13  2
  1991COH/WES1211-1311   CF3CHCl2 + ·OHH2O + CF3CCl2  250 - 2000   1.18E-13   1.70   3076   3.40E-14  2
  1991COH/WES1211-1311   C2H5F + ·OH → Other Products + H2O  298 - 2000   1.40E-12   1.60   4573   2.22E-13  2
  1991COH/WES1211-1311   C2F5H + ·OHC2F5 + H2O  298 - 2000   2.11E-13   1.60   1.06E04   2.97E-15  2
  1991COH/WES1211-1311   CHF2CHF2 + ·OHH2O + CHF2CF2  298 - 2000   4.27E-13   1.70   1.11E04   4.92E-15  2
  1991COH/WES1211-1311   CH3CF3 + ·OHCF3CH2 + H2O  298 - 2000   3.59E-12   1.10   1.98E04   1.22E-15  2
  1991COH/WES1211-1311   CH2FCHF2 + ·OH → Other Products + H2O  298 - 2000   8.29E-13   1.70   7732   3.66E-14  2
  1991COH/WES1211-1311   neo-C5H12 + ·OH + Neopentyl  298 - 2000   6.36E-12   2.50   2.26E04   6.91E-16  2
  1991COH/WES1211-1311   CH3F + ·OH·CH2F + H2O  250 - 2000   2.23E-12   1.50   1.23E04   1.55E-14  2
  1991COH/WES1211-1311   CH2FCl + ·OHH2O + ·CClFH  250 - 2000   8.45E-13   1.60   7234   4.56E-14  2
  1991COH/WES1211-1311   (CH3)3CC(CH3)3 + ·OH + (CH3)3CC(CH3)2CH2  298 - 2000   8.15E-12   2.50   1.96E04   2.96E-15  2
  1991COH/WES1211-1311   CH2FCH2F + ·OHH2O + CH2FCHF  298 - 2000   1.66E-12   1.70   6735   1.09E-13  2
  1991COH/WES1211-1311   CF3CH2F + ·OHH2O + CF3CHF  250 - 2000   5.60E-13   1.70   1.17E04   4.93E-15  2
  1991COH/WES1211-1311   CF2ClCH2Cl + ·OH → ·CHClCClF2 + H2O  250 - 2000   4.00E-13   1.70   6735   2.64E-14  2
  1991COH/WES1211-1311   ·CH3 + ·OHCH4 +   298 - 2500   3.22E-14   2.20   1.86E04   1.75E-17  2
  1991COH/WES1211-1311   CF3CHFCl + ·OH → CF3CFCl· + H2O  250 - 2000   1.34E-13   1.70   6402   1.01E-14  2
  1991COH/WES1211-1311   ·OH + NH3H2O + NH2  225 - 3000   7.56E-13   1.60   3991   1.51E-13  2
  1991COH/WES1211-1311   ·OH + NH2NH3 +   298 - 2000   4.95E-15   2.60   -7234   9.17E-14  2
  1991COH/WES1211-1311   ·OH + NH2H2O + NH  250 - 3000   7.69E-13   1.50   -1912   1.66E-12  2
  1991COH/WES1211-1311   ·OH + NHH2O + N  298 - 3000   3.09E-12   1.20       3.09E-12  2
  1991COH/WES1211-1311   ·OH + NH + HNO  298 - 3000   3.32E-11           3.32E-11  2
  1991COH/WES1211-1311   ·OH + NHNH2 +   298 - 3000   2.94E-12   0.10   4.82E04   1.04E-20  2
  1991COH/WES1211-1311   ·C2H5 + ·OHC2H6 +   298 - 1500   9.85E-19   8.80   2079   4.26E-19  2
  1991COH/WES1211-1311   ·OH + NNH +   500 - 3000   1.88E-11   0.10   8.90E04      2
  1991COH/WES1211-1311   NH3 + ·OH + NH2  298 - 2000   2.87E-13   2.10   2.18E04   4.37E-17  2
  1991COH/WES1211-1311   H2O + NH2·OH + NH3  300 - 3000   2.09E-13   1.90   4.76E04      2
  1991COH/WES1211-1311   H2O + NH·OH + NH2  600 - 3000   1.81E-12   1.60   1.17E05      2
  1991COH/WES1211-1311   H2O + N·OH + NH  800 - 3000   6.03E-11   1.20   1.60E05      2
  1991COH/WES1211-1311   NO + NH +   1300 - 3000   9.30E-10   -0.10   2.93E05      2
  1991COH/WES1211-1311   + HNO·OH + NH  350 - 3000   2.41E-09   -0.50   7.49E04      2
  1991COH/WES1211-1311   + HNONH2 +   550 - 3000   1.05E-09   -0.30   1.22E05      2
  1991COH/WES1211-1311   NH2 + → Products  298 - 3000   8.80E-11           8.80E-11  2
  1991COH/WES1211-1311   NH2 + H2 + NO  298 - 3000   8.30E-12           8.30E-12  2
  1991COH/WES1211-1311   NH2 + ·OH + NH  298 - 3000   1.16E-11           1.16E-11  2
  1991COH/WES1211-1311   NH2 + + HNO  298 - 3000   7.47E-11           7.47E-11  2
  1991COH/WES1211-1311   NH + ·OH + N  250 - 3000   1.16E-11           1.16E-11  2
  1991COH/WES1211-1311   NH + NO +   250 - 3000   1.16E-10           1.16E-10  2

Search returned 68 records.