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Accessibility information
Author(s):   Cohen, N.
Title:   Are reaction rate coefficients additive? Revised transition state theory calculations for OH + alkane reactions
Journal:   Int. J. Chem. Kinet.
Volume:   23
Page(s):   397 - 417
Year:   1991
Reference type:   Journal article
Squib:   1991COH397-417

Reaction:   n-C8H18 + ·OHH2O + 3-C8H17
Reaction order:   2
Temperature:   298 - 1000 K
Rate expression:   7.75x10-13 [cm3/molecule s] (T/298 K)2.00 e5654 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 7.60E-12
300 7.58E-12
350 7.47E-12
400 7.65E-12
450 8.01E-12
500 8.51E-12
550 9.10E-12
600 9.76E-12
650 1.05E-11
700 1.13E-11
750 1.22E-11
800 1.31E-11
850 1.40E-11
900 1.51E-11
950 1.61E-11
1000 1.72E-11