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Author(s):   DeMore, W.B.
Title:   Tests of stratospheric models: The reactions of atomic chlorine with O3 and CH4 at low temperature
Journal:   J. Geophys. Res.
Volume:   96
Page(s):   4995 - 5000
Year:   1991
Reference type:   Journal article
Squib:   1991DEM4995-5000

Reaction:   CH3O2· + ClOCH3 + ClOO
Reaction order:   2
Temperature:   197 - 217 K
Pressure:  1.01 - 3.04 bar
Rate expression:   4.0x10-12 [cm3/molecule s]
Rate constant is an upper limit.
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   IR absorption

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