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Accessibility information
Author(s):   Koppenkastrop, D.; Zabel, F.
Title:   Thermal decomposition of chlorofluoromethyl peroxynitrates
Journal:   Int. J. Chem. Kinet.
Volume:   23
Page(s):   1 - 15
Year:   1991
Reference type:   Journal article
Squib:   1991KOP/ZAB1-15

Reaction:   CClF2OONO2NO2 + CClF2OO
Reaction order:   2
Temperature:   264 - 288 K
Pressure:  1.00E-2 - 0.80 bar
Rate expression:   1.79x10-3 [cm3/molecule s] e-87302 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
264 9.56E-21
275 4.69E-20
288 2.63E-19