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Author(s):   Korobkov, V.Y.; Kalechits, I.V.
Title:   Kinetics of the thermolysis of para-substituted 1,2-diarylethanes. Effect of substituents on the strenght of the CH2-CH2-bond
Journal:   Russ. J. Phys. Chem. (Engl. Transl.)
Volume:   65
Page(s):   346 - 351
Year:   1991
Reference type:   Journal article
Squib:   1991KOR/KAL346-351

Reaction:   Benzene, 1,1'-(1,2-ethanediyl)bis[4-methyl-4-Methylbenzyl + 4-Methylbenzyl
Reaction order:   1
Temperature:   683 - 713 K
Pressure:  0.85 bar
Rate expression:   9.86x1014 [s-1] e-253591 [J/mole]/RT
Bath gas:   1,2,3,4-Tetrahydronaphthalene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
683 3.98E-5
700 1.18E-4
713 2.61E-4