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Accessibility information
Author(s):   Nielsen, O.J.
Title:   Rate constants for the gas-phase reactions of OH radicals with CH3CHF2 and CHCl2CF3 over the temperature range 295-388 K
Journal:   Chem. Phys. Lett.
Volume:   187
Page(s):   286 - 290
Year:   1991
Reference type:   Journal article
Squib:   1991NIE286-290

Reaction:   CF3CHCl2 + ·OHH2O + CF3CCl2
Reaction order:   2
Temperature:   295 - 388 K
Pressure:  1.01 bar
Rate expression:   1.1x10-12 [cm3/molecule s] e-7816 [±1638 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Ultrasonics
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
295 4.54E-14
300 4.79E-14
325 6.10E-14
350 7.49E-14
375 8.96E-14
388 9.75E-14